Luminescence of Blue-purple Emitting Sr2SiO4：Ce3＋,Li＋Phosphor

YOU Jing,XIA Li-na,LI Xiang-qi,2*,XIE Xiu-zhen

（1.College of Mɑteriɑls Science ɑnd Engineering,Fuzhou Uniυersity,Fuzhou 350108,Chinɑ; 2.Key Lɑborɑtory of Eco-mɑteriɑls Adυɑnced Technology,Fuzhou Uniυersity,Fuzhou 350108,Chinɑ）*Corresponding Author,E-mɑil:lxiɑngqi@fzu.edu.cn

Luminescence of Blue-purple Emitting Sr2SiO4：Ce3＋,Li＋Phosphor

YOU Jing1,XIA Li-na1,LI Xiang-qi1,2*,XIE Xiu-zhen1

（1.College of Mɑteriɑls Science ɑnd Engineering,Fuzhou Uniυersity,Fuzhou 350108,Chinɑ; 2.Key Lɑborɑtory of Eco-mɑteriɑls Adυɑnced Technology,Fuzhou Uniυersity,Fuzhou 350108,Chinɑ）*Corresponding Author,E-mɑil:lxiɑngqi@fzu.edu.cn

Blue-PurPle emitting Sr2-xSiO4：xCe3＋（x＝0.01-0.09，in steps of 0.01）and Sr1.95-ySiO4：0.05Ce3＋，yLi＋（y＝0.01-0.07，in stePs of 0.02）phosphors have been PrePared by co-PreciPitation method with MCM-41 as silica source.The emission spectra of Sr2-xSiO4：xCe3＋show an asYmmetric broad band with a maximum around 410 nm and the critical mole fraction is found to be 5%.Ce3＋ions Prefer nine-coordinated Sr（Ⅱ）sites over ten-coordinated Sr（Ⅰ）sites.The emission intensitY of Sr1.95SiO4：0.05Ce3＋can be imProved effectivelY by co-doPing Li＋ions as charge comPensator and a greater degree of the imProvement is observed for PhosPhor calcined at 1 100℃comPared with 1 000℃.The most suitable doPing amount of Li＋for Sr1.95-ySiO4：0.05Ce3＋，yLi＋is y＝0.05.

PhosPhor;Sr2SiO4：Ce3＋，Li＋;luminescence

1　Introduction

As a new tYPe of solid light source，white light emitting diodes（WLEDs）have attracted much attention due to high Power efficiencY，energY saving and environment-friendliness etc.ComPared with the WLEDs based on Yellow YAG phosphors combined with a blue InGaN LED chiP，the NUV-excitedblends of blue-，green-，and red-emitting phosphors have the higher color reProduction and color rendering[1-4].As a good candidate excited in the NUV range，Sr2SiO4matrix PhosPhor is extensivelY studied because of its good chemical stabilitY and thermal stabilitY[5-10].

The commonly doPed rare-earth luminescentcenters in Sr2SiO4matrix include Eu2＋，Eu3＋，Ce3＋，DY3＋，etc.Sr2SiO4：Eu2＋is one of the Prevailinggreen-YellowphosphorsforWLEDs[8]. Sr1.97-（x＋y）DY0.03CexLiySiO4can emit colour from blue-white to orange-white by varYing DY3＋concentration[9].The non-equivalent substitution of divalent ion by trivalent ion would create vacancies，which quench the luminescence.Reports show that co-doping of charge compensator（Li＋，Na＋，K＋）can solve this Problem and enhance the emission intensities of phosphors，such as Sr2SiO4：Tb3＋[10]，Sr3B2O6：Ce3＋，Eu2＋[11]，（Ba1-xSrx）9Sc2Si6O24：Ce3＋[12]，and Sr2SiO4：Sm3＋[13].In addition to charge comPensator，the luminescence of rare-earth ions doPed Sr2SiO4is also influenced by the local coordination of the rare-earth ions in the host lattice. Sr2SiO4exists in two crYstalline Phases:β-Sr2SiO4（monoclinic）and α′-Sr2SiO4（orthorhombic）.β-Sr2SiO4Phase is the low temperature Phase while α′-Sr2SiO4Phase the high temperature one[14].There are two kinds of cation sites for Sr2＋in both α′and β Phases.Sr（Ⅰ）is ten-coordinated and Sr（Ⅱ）is nine-coordinated by oxYgen atoms[15].The amount of Sr（Ⅰ）site is equal to that of Sr（Ⅱ）site.For Sr（Ⅰ）site the average Sr—O bond distance is 0.285 2 nm in α′Phase and 0.285 0 nm in β Phase.For Sr（Ⅱ）site the average Sr—O bond distance is 0.269 8 nm in α′Phase and 0.270 9 nm in β Phase[16].Since the ionic radius of the Ce3＋（0.125 nm，10 coord.）is verY similar to ionic radius of the Sr2＋（0.132 nm，10 coord.），Ce3＋ions substitute Sr2＋ions in Sr2SiO4lattice[17].

The commercial Sr2SiO4phosphors are commonly Produced by the conventional solid-state reaction methodinvolvingcalciningattemperatures above 1 200℃[6-8].RePorts show that the sYnthesized temperature of the silicate phosphors can be loweredbyusingmesoPoroussilicaasSi source[18-19].In this PaPer，we sYnthesized Sr2SiO4：Ce3＋，Li＋phosphors at 1 000 or 1 100℃，using MCM-41 as silicon source.The relationshiPs between emission ProPertY and Ce3＋concentration as well as Li＋concentration are discussed.The influence of temperature on emission intensitY is also studied.

2　ExPeriments

2.1Preparation

MCM-41 was sYnthesized as follows:tetraethYl orthosilicate（TEOS）was added under constant stirring to a mixing solution of cetYltrimethYlammonium bromide（CTAB），ammonia solution and distilled water.After stirred for 1 h at room temperature，the solution was sealed in a Teflon-lined stainless steel autoclave and heated at 110℃for 48 h.The solid PreciPitate was filtered，washed，dried and calcined in air at 550℃for 6 h.The molar ratio of the reactants was n（CTAB）：n（TEOS）：n（NH3?H2O）：n（H2O）＝0.24：0.075：0.01：66.7.

The Sr2-xSiO4：xCe3＋（x＝0.01-0.09，in stePs of 0.01）and Sr1.95-ySiO4：0.05Ce3＋，yLi＋（y＝0.01-0.07，in stePs of 0.02）phosphors were PrePared as follows:Sr（NO3）2，LiNO3，and Ce（NO3）3（0.1 mol/L）solution were mixed in deionized water to get a homogenized solution A.Amount of MCM-41 and oxalic acid（n（MCM-41）：n（oxalic acid）＝1：1.5，molar ratio），ammonia solution was uniformlY mixed in deionized water as solution B，sonicating for about 25 min.Then solution A was added droPwise to the solution B under vigorous stirring.After stirred for 1 h and then stilled at room temperature for 2 h，the Products were filtered，washed，dried，and calcined at 1 000 or 1 100℃for 3 h in the carbon reduction atmosPhere.

2.2Characterizations

X-raY Powder diffraction（XRD）measurements were Performed on the Rigaku D/MAX-Ultima S equiPPed with Cu Ka radiation（40 kV，20 mA），at the rate of 2.0（°）/min over the range of 1°-8°（2θ），and 6.0（°）/min over the range of 20°-70°（2θ）.The Particle morPhologY and size were measured using a thermal field emission electron microscoPe（SUPRA 55，Carl Zeiss，GermanY）at an accelerating voltage of 3.00 kV.The excitation and emission spectra were measured on a FluoroMax-4 fluorescent sPectroPhotometer with a slit width of 0.8 nm and a Xe lamP as light source.The quantum efficiencY was measured by a FluoroMax-4 fluorescent sPectroPhotometer.All the samPles were measured at room temperature.

3　Results and Discussion

XRD Pattern of MCM-41 Powder is shown in Fig.1.It can be observed that there are three wellresolved Peaks at 2θ range of 1°-5°，indexed as（100），（110）and（200）reflections of the hexagonal Phase MCM-41[20].This indicates that the sYnthesized samPlePossesses tYPical mesoPorous structure of MCM-41.

Fig.1　XRD Pattern of MCM-41

Fig.2　XRD Patterns of Sr2-xSiO4：xCe3＋samPles calcined at 1 100℃

XRD Patterns of Sr2-xSiO4：xCe3＋samPles calcined at 1 100℃are shown in Fig.2.For x＝0.01 samPle，major β-Sr2SiO4Phase co-exists with minor α′-Sr2SiO4Phase.When x increased to 0.03，the intensitY of diffraction Peaks of β-Sr2SiO4decreased. When x is higher than 0.03，the β-Sr2SiO4Phase comPletelY transformsintothePureα′-Sr2SiO4Phase，and a weak Peak at 2θ＝28.6°，assigned to the（111）diffraction of the CeO2Phase，can be clearlY observed.

XRD Patterns of Sr1.95SiO4：0.05Ce3＋and Sr1.9-SiO4：0.05Ce3＋，0.05Li＋samPles calcined at different temperatures are Presented in Fig.3.All the three samPles consist of nearlY Pure α′-Sr2SiO4Phase with onlY minor CeO2imPuritY Phase.ComPared to the Sr1.95SiO4：0.05Ce3＋samPle calcined at 1 000℃，the diffraction Peaks of Sr1.95SiO4：0.05Ce3＋and Sr1.9SiO4：0.05Ce3＋，0.05Li＋calcined at 1 100℃shift to the higher angle-side，indicating the lattice shrinking with rising calcining temperature.

Fig.3　XRD Patterns of Sr1.95SiO4：0.05Ce3＋and Sr1.9SiO4：0.05Ce3＋，0.05Li＋samPles calcined at different temperatures

The structure of α′-Sr2SiO4is similar to that of β-K2SiO4and has been described in literature[21-22]. The schematic crYstal structure of α′-Sr2SiO4Phase is shown in Fig.4（a）.There are two cation sites of Sr2＋in α′-Sr2SiO4Phase.Sr（Ⅰ）is 10-coordinated and Sr（Ⅱ）is 9-coordinated by oxYgen atoms，as shown in Fig.4（b）.

SEM images of Sr1.95SiO4：0.05Ce3＋samPles calcined at different temperatures are shown in Fig. 5.For samPles calcined at 1 000℃，the Particle diameters are about 2.3 μm and the shaPe is regular. As the calcining temperature increased from 1 000℃to 1 100℃，the Particle sizes increase from 2.3 μm to 4.2 μm，and the shaPe is also regular.ComPared with the samPle calcined at 1 000℃，the samPle at1 100℃shows cleaner Particle surfaces and more straight grain boundaries.It indicates that the sam-Ple calcined at 1 100℃has better crYstallinitY.

Fig.6shows the emission and excitation spectra of the Sr2-xSiO4：xCe3＋samPles calcined at 1 100℃.All the excitation spectra show two bands at about 280 nm and 351 nm，corresPonding to the 4f-5d transition of Ce3＋.The emission spectra show an asYmmetric broad band with a maximum locating at around 410 nm，ascribed to the 5d-4f transition of Ce3＋.The emission Peak shifts towards red with increasing x.The emission intensitY and half-band width increase significantlY with increasing Ce3＋concentration，and graduallY decrease as x exceeding 0.05.This shows that 5%Ce3＋is a critical concentration in Sr2SiO4.

Fig.4　（a）Schematic crYstal structure of α′-Sr2SiO4Phase.（b）Coordination environments of Sr（Ⅰ）and Sr（Ⅱ）sites in α′Phase.

Fig.5　SEM images of Sr1.95SiO4：0.05Ce3＋samPles calcined at different temperatures

Fig.6　Emission and excitation spectra of Sr2-xSiO4：xCe3＋samPles calcined at 1 100℃

The emission sPectrum of Sr1.95SiO4：0.05Ce3＋could be decomPosed into two Gaussian Peaks centered at 398 nm and 424 nm，resPectivelY，as shown in Fig.7.According to Van Uitert's emPirical equation[23]shown below，the emission wavelength of Ce3＋in Sr2SiO4host could be calculated to identifY the sites of Ce3＋ions.

Fig.7　Gaussian Peak fittings for emission sPectrum of Sr1.95-SiO4：0.05Ce3＋calcined at 1 100℃

Q is the Position in energY for the lower d-band edge for the free ion（50 000 cm-1for Ce3＋）.V is the valance of the activator，and is 3 for Ce3＋ion.n is the coordination number of the host cation.r is the radius of the host cation rePlaced by Ce3＋ion.eɑ is the electron affinitY of the atoms that form anions（1.6 eV for O2-）.The ionic radius of 10-and 9-coordinated Sr2＋are 0.132 nm and 0.125 nm，resPectivelY[16].The calculated Peaks of Ce3＋in ten-coordinated Sr（Ⅰ）and nine-coordinated Sr（Ⅱ）are located at 396 nm and 436 nm，resPectivelY. The observed emission Peaks at 398 nm and 424 nm are in verY good agreement with the calculated Peaks，and can be attributed to the Ce3＋（Ⅰ）and Ce3＋（Ⅱ），resPectivelY.The result indicates that Ce3＋ions occuPY the two different sites of Sr2＋in Sr2SiO4host.

The Gaussian fitting results for the spectra of Sr2-xSiO4：xCe3＋phosphors are summarized in Tab. 1.As shown in Tab.1，when the content of Ce3＋increases in the range of 0.01 to 0.05，the ratio of integral area of Gaussian fitting Peak Ce3＋（Ⅰ）to Ce3＋（Ⅱ）decreases，indicating a Preference for Ce3＋to occuPY the smaller Sr（Ⅱ）site rather than the larger Sr（Ⅰ）site in the solid solution.The radius of Ce3＋is smaller than that of Sr2＋.The Preferent occuPation of smaller Sr2＋（Ⅱ）by Ce3＋can reduce lattice distortion.

Tab.1 Gaussian fitting results for the spectra of Sr2-x-SiO4：xCe3＋phosphors

The emission spectra of Sr1.95SiO4：0.05Ce3＋and Sr1.9SiO4：0.05Ce3＋，0.05Li＋calcined at different temperatures are Presented in Fig.8.As the calcining temperature increased from 1 000℃to 1 100℃，the emission intensities of phosphors enhance obviouslY.This can be attributed to the im-Proved crYstallinitY.It can also be observed from Fig.8that the emission intensitY of Sr1.9SiO4：0.05Ce3＋，0.05Li＋is much higher than that of Sr1.95SiO4：0.05Ce3＋calcined at the same temperature.DoPing Li＋ions can obviouslY imProve the emission intensitY.The degree of imProvement is influenced by the calcining temperature.ObviouslY， doPing Li＋ions imProve the emission intensitY of Sr1.95SiO4：0.05Ce3＋calcined at 1 100℃more effectivelY than that calcined at 1 000℃.

Fig.8　Excitation and emission spectra of Sr1.95SiO4：0.05Ce3＋and Sr1.9SiO4：0.05Ce3＋，0.05Li＋calcined at different temperatures

Fig.9shows the emission spectra of Sr1.95-ySiO4：0.05Ce3＋，yLi＋under 351 nm excitation.It can be seen that all the samPles show the characteristic emission of Ce3＋at 410 nm and no distinct diversifications on the shaPes and Positions of the emission spectra are observed.The emission intensities of Sr1.95-ySiO4：0.05Ce3＋，yLi＋increase with increasing y，and graduallY decrease as the doPing concentration of Li＋exceeds y＝0.05.The intensitY of samPle with y＝0.05 shows the highest intensitY，two times as high as that of samPle with y＝0.The results indicate that the most suitable doPing amount for Li＋is equal to that for Ce3＋.The non-equivalent substitution of Sr2＋by Ce3＋can lead to the advent of Sr2＋vacancY，which acts as the charge traPPing center and hence quenches the luminescence.When the monovalent alkali metal ion Li＋is co-doPed as the charge comPensator，the number of the vacancies decreases with increasing concentration of Li＋，and the emission intensitY is therefore imProved[24-26].

Fig.9　Emission spectra of Sr1.95-ySiO4：0.05Ce3＋，yLi＋

The internal quantum efficiencY（IQE）was measured using the excitation source of 351 nm.The IQE of Sr1.95SiO4：0.05Ce3＋and Sr1.9SiO4：0.05Ce3＋，0.05Li＋calcined at 1 100℃were obtained to be 23.7%and 35.7%，resPectivelY.The result suggests that doPing ProPer amount of Li＋ions is an effective method to enhance the IQE of Sr2SiO4：Ce3＋PhosPhor.

The measured chromaticitY coordinates（xc，yc）of Sr2-x-ySiO4：xCe3＋，yLi＋phosphors are summarized in Tab.2.The CIE chromaticitY diagram of Sr1.95-yLiySiO4：0.05Ce3＋phosphors is shown in Fig.10.It can be seen that all the samPles exhibit blue-PurPle emissions.The variation of Li＋doPing concentration onlY influences the emission intensitY and has little effect on the colorimetric coordinate location in the CIE chromaticitY diagram.

Tab.2 Chromaticity coordinates（xc，yc）of Sr2-x-ySiO4：xCe3＋，yLi＋phosphors

Fig.10 CIE chromaticitY coordinates of Sr1.95-yLiySiO4：0.05Ce3＋PhosPhors

4　Conclusion

Sr2-xSiO4：xCe3＋and Sr1.95-ySiO4：0.05Ce3＋，yLi＋phosphors have been PrePared at 1 000 or 1 100℃.For Sr2-xSiO4：xCe3＋samPles，major β-Sr2SiO4Phase co-exists with minor α′-Sr2SiO4Phase when x＝0.01，and the α′-Sr2SiO4Phase comPletelY transforms into β-Sr2SiO4Phase when x＞0.03.All the samPles exhibit blue-PurPle emissions.The critical mole fraction of Ce3＋is found to be 5%.DoPing ProPer amount of Li＋ions can imProve the emission intensitY of Sr1.95SiO4：0.05Ce3＋calcined at 1 100℃more effectivelY than that at 1 000℃.The most suitable doPing amount of Li＋for Sr1.95-ySiO4：0.05Ce3＋，yLi＋is y＝0.05.The results in Present work could be helPful for efficiently enhancing the luminescence of Sr2SiO4：Ce3＋PhosPhor.

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游靜（1990-），女，福建漳州人，碩士研究生，2013年于昆明理工大學獲得學士學位，主要從事稀土摻雜硅酸鹽基質發光材料方面的研究。

E-mail:Youjing186@126.com

李湘祁（1968-），女，湖南宜章人，副教授，1990年于中南工業大學（現中南大學）獲得博士學位，主要從事介孔材料、硅酸鹽基質發光材料的合成應用方面的研究。

E-mail:lxiangqi@fzu.edu.cn

1000-7032（2016）02-0131-07

Sr2SiO4：Ce3＋,Li＋藍紫色熒光粉發光性能的研究

游 靜1,夏麗娜1,李湘祁1,2*,謝秀珍1

（1.福州大學材料科學與工程學院，福建福州 350108; 2.福州大學生態環境材料先進技術重點實驗室，福建福州 350108）

以MCM-41為硅源，采用共沉淀法制備Sr2-xSiO4：xCe3＋（x＝0.01～0.09，步長為0.01）和Sr1.95-ySiO4：0.05Ce3＋，yLi＋（y＝0.01～0.07，步長為0.02）藍紫色熒光粉。Sr2-xSiO4：xCe3＋的發射光譜是一個不對稱的寬帶，最大峰值在410 nm左右。Ce3＋的最佳摻雜量為5%。Ce3＋離子傾向于占據九配位的Sr（Ⅱ）格位。共摻電荷補償劑Li＋可以有效地提高Sr1.95SiO4：0.05Ce3＋的發光強度，其中Li＋離子對1 100℃煅燒樣品的發光強度的提高程度比1 000℃的更高，Li＋的最佳摻雜量為y＝0.05。

熒光粉;Sr2SiO4：Ce3＋，Li＋;發光

2015-11-20;

2015-12-08

O482.31 Document code:A DOI:10.3788/fgxb20163702.0131